Article

Researchers at the Chinese Academy of Agricultural Sciences utilized a high-temperature pyrolysis reactor with a tailored catalyst bed to process corn straw, achieving gas yields exceeding 70% by weight and hydrogen concentrations up to 45.24% by volume. The introduction of biochar as a pre-catalyst layer increased the hydrogen fraction to 48.87% by volume.

This configuration allows biochar to act as a reactive filter, adsorbing tar molecules and enhancing the quality of the feed to nickel catalysts. The study found that gas yields improved by nearly 9 percentage points with biochar pre-catalysis, while tar yields declined across all catalyst formulations.

A techno-economic assessment indicated a net benefit of $0.31 per kilogram of biomass processed with biochar, contrasting with a loss of $2.72 per kilogram without it due to higher catalyst costs and reduced gas output. The authors suggest that recycling biochar could mitigate catalyst demand and enhance sustainability in biorefineries.